Template-free Synthesis of Nanoporous Metals

Nanoporous metals represent an interesting class of materials with potential applications in catalysis, hydrogen storage, fuel cells, and separations. To date, such structures have been made via time consuming approaches involving the use of sacrificial scaffolds that are ultimately removed. Northwestern researchers have developed a simple, one-pot synthesis of nanoporous metals taking advantage of plastic properties of their nanoparticles. The method is applicable to nanoporous stuctures of various porosities, and made of different metals, as well as their mixtures.

nanoporous

Electron microscopy images showing the structural evolution of nanoparticles leading to nanoporous metals.

 

Rafal Klajn, Timothy P. Gray, Paul J. Wesson, Benjamin D. Myers, Vinayak P. Dravid, Stoyan K. Smoukov, Bartosz A. Grzybowski, “Bulk Synthesis and Surface Patterning of Nanoporous Metals and Alloys from Supraspherical Nanoparticle Aggregates," Adv. Funct. Mater., 18, 2763 (2008). ABSTRACT

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The Materials Research Science and Engineering Center (MRSEC) is supported by the National Science Foundation under NSF Award Number DMR-0520513. Any opinions, findings and conclusions or recommendations expressed in this material are those of the author(s) and do not necessarily reflect those of the National Science Foundation.
© 2008 Northwestern University